β,β′-fusion induced unique out-of-plane platinum(II) complexation in porphycene

Autor:	Pradeepta K. Panda, Sameeta Sahoo
Rok vydání:	2022
Předmět:	Fusion Ethylene Large deformation Ligand chemistry.chemical_element Ring (chemistry) Electrochemistry Inorganic Chemistry Out of plane chemistry.chemical_compound Crystallography chemistry Materials Chemistry Physical and Theoretical Chemistry Platinum
Zdroj:	Inorganica Chimica Acta. 530:120679
ISSN:	0020-1693
Popis:	Herewith, the first out-of-plane platinum(II) complex of dinaphthoporphycene (DNP) is reported. Instead of the usual N4 coordination, porphycene acts as a bidentate ligand and platinum(II) opts to coordinate across the ethylene bridge, forming a seven membered ring with the ligand. The planar ligand undergoes large deformation to adopt a bowl shape during complexation, while platinum(II) still maintaining the square planar geometry. Photophysical properties and electrochemical analysis of this complex are also explored.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::34b9f27829a01bdb7525e4fda158006b https://doi.org/10.1016/j.ica.2021.120679 Zobrazit plný text záznamu Full Text from ScienceDirect