Type-II band alignment of low-boron-content BGaN/GaN heterostructures

Autor: A. Kadys, Jūras Mickevičius, R. Tomašiūnas, O. Ligor, E. M. Pavelescu, Mindaugas Andrulevičius, Gintautas Tamulaitis
Rok vydání: 2019
Předmět:
Zdroj: Journal of Physics D: Applied Physics. 52:325105
ISSN: 1361-6463
0022-3727
DOI: 10.1088/1361-6463/ab2337
Popis: The band offset parameters of low-boron-content BGaN/GaN heterojunctions have been studied using x-ray photoelectron spectroscopy (XPS) and photoluminescence (PL) in BxGa1−xN epilayers (x ≤ 0.043) grown on GaN/sapphire and AlN/sapphire templates. A staggered-gap (type-II) band alignment has been identified at the BGaN/GaN heterojunction by XPS. A study of the red shift of deep-level-related yellow PL band and the band gap shrinkage of BGaN epilayers with increasing boron content confirmed the type-II band alignment and enabled us to estimate that the ratio of the conduction-to-valence band discontinuity is 57:43. It is also shown that the band gap bowing of the BGaN alloy system is accommodated in the conduction band.
Databáze: OpenAIRE