Reaktionen von Diphenylsulfilimin Ph2SNH mit Carbonylmetallkomplexen/ Reactions of Diphenylsulfilimine Ph2SNH with Carbonyl Metal Complexes

Autor:	Wolfgang Beck, Günter Urban
Rok vydání:	1982
Předmět:	Metal Chemistry visual_art visual_art.visual_art_medium General Chemistry Medicinal chemistry
Zdroj:	Zeitschrift für Naturforschung B. 37:1101-1103
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-1982-0901
Popis:	The reaction of the carbonyl metal hydrides (π - C5H5)M (CO)3H(M = Mo, W) with Ph2S = XH gives the ainine-isoeyanato compounds (π - C5H5)(CO)2M(NH3)NCO. N-Carbaxnoyl-B,S-diphenylsulfilimine Ph2S N-C(O) NH2 has boon isolated from the reaction of the hexacarbonyls M(CO)6(M=Cr,Mo) with Ph2S = XH. The spectroscopic data (IR, 1H, 13C NMR, MS) are reported and the formation of the products is discussed.
Databáze:	OpenAIRE
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