Solid-phase mechanochemical synthesis of zirconium tetracarboxylates
Autor: | P. E. Matkovskii, L. A. Petrova, V. D. Sasnovskaya, Viktor D. Makhaev |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Russian Chemical Bulletin. 59:1735-1739 |
ISSN: | 1573-9171 1066-5285 |
DOI: | 10.1007/s11172-010-0305-y |
Popis: | The solid-phase synthesis of zirconium carboxylates Zr(OOCR)4 (R = Alk) by reactions of zirconium tetrachloride with metal carboxylates (isobutyrate, pivalate, and palmitate) (the molar ratio ZrCl4: RCOOM is 1: (4–5)) under mechanical activation is developed. Further thermal treatment of the reaction mixture and extraction with an organic solvent afford zirconium carboxylates. |
Databáze: | OpenAIRE |
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