ChemInform Abstract: Diepoxy(15)annulenones Undergo Photochemical Carbonyl-O/Divinyl Ether- O Transportation Rearrangements: Mechanistic Probing of the Rearrangement Sequences Facilitated by 13C/17O NMR Spectroscopy

Autor: Taiji Imoto, Yuko Kato, Yasuyoshi Nogami, Hideaki Ogawa, Toru Koga, Yuko Ohokubo
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 26
ISSN: 0931-7597
Popis: On irradiation, diepoxy[15]annulenone 1 and monobromo-diepoxy[15]annulenone 2 undergo an intriguing rearrangement, whereby all of the ether and carbonyl oxygens of 1 and 2 can travel freely and change their positions in the rings to give 15 position isomers in all.
Databáze: OpenAIRE