A thermodynamic study of complexation reaction of yttrium(III), lanthanum(III) and cerium(III) with tyrosine
Autor: | Ranjit Singh Sandhu |
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Rok vydání: | 1977 |
Předmět: | |
Zdroj: | Monatshefte f�r Chemie. 108:51-55 |
ISSN: | 1434-4475 0026-9247 |
DOI: | 10.1007/bf00900906 |
Popis: | The thermodynamic stability constants and thermodynamic parameters for complexation reaction of Y3+, La3+, and Ce3+ with tyrosine have been determined pH metrically. The study reveals the formation of 1∶1 complexes for La3+ and Ce3+ whereas Y3+ yields both 1∶1 and 1∶2 complexes. The values of enthalpy changes (ΔHo) indicate that unionised hydroxy group also participates in complexation. |
Databáze: | OpenAIRE |
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