A thermodynamic study of complexation reaction of yttrium(III), lanthanum(III) and cerium(III) with tyrosine

Autor: Ranjit Singh Sandhu
Rok vydání: 1977
Předmět:
Zdroj: Monatshefte f�r Chemie. 108:51-55
ISSN: 1434-4475
0026-9247
DOI: 10.1007/bf00900906
Popis: The thermodynamic stability constants and thermodynamic parameters for complexation reaction of Y3+, La3+, and Ce3+ with tyrosine have been determined pH metrically. The study reveals the formation of 1∶1 complexes for La3+ and Ce3+ whereas Y3+ yields both 1∶1 and 1∶2 complexes. The values of enthalpy changes (ΔHo) indicate that unionised hydroxy group also participates in complexation.
Databáze: OpenAIRE