Photochemical reactions of monomeric and dimeric radical cations of acetone in freon matrices at 77 K

Autor:	Elena N. Seropegina, Michail Ya. Mel’nikov, D. V. Baskakov, Vladilen N. Belevskii, Sergei I. Belopuschkin
Rok vydání:	1996
Předmět:	Matrix (mathematics) chemistry.chemical_compound Monomer Freon chemistry Radical Acetone General Chemistry Photochemistry
Zdroj:	Mendeleev Communications. 6:183-185
ISSN:	0959-9436
DOI:	10.1070/mc1996v006n05abeh000636
Popis:	Monomeric [ λ max ≃ 435 nm, ɛ max ≃ (3.6 ± 0.6) × l0 3 dm 3 mol −1 cm −1 ] and dimeric [ λ max ≃ 715 nm, ɛ max ≃ (9.4 ± 1.2) × l0 3 dm 3 mol −1 cm −1 ] radical cations of acetone in a freon matrix at 77 K under the action of light react to form matrix radical cations and acetonyl radicals CH 2 COMe with quantum yields of Φ > (4.0 ± 1.0) × l0 −3 and Φ > (2.0 ± 1.0) × l0 −2 , respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::33ab3e2a230f12f5b18c990bc352360f https://doi.org/10.1070/mc1996v006n05abeh000636 Zobrazit plný text záznamu Full Text from ScienceDirect