The synthesis of heliannuol C, an allelochemical from Helianthus annuus

Autor:	Ramanathapuram V. Venkateswaran, Amalesh Roy, Prabir K. Sen, Bidyut Biswas
Rok vydání:	2006
Předmět:	Claisen rearrangement Ring-closing metathesis Chemistry Stereochemistry Organic Chemistry Drug Discovery Condensation Helianthus annuus Total synthesis Ring (chemistry) Biochemistry
Zdroj:	Tetrahedron Letters. 47:4019-4021
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2006.04.011
Popis:	The synthesis of the allelochemical heliannuol C 1 is described by employing a Bargellini condensation and a Claisen rearrangement to install the gem-dimethyl and vinyl functionalities, respectively. A Dieckmann cyclisation of diester 11 enabled the generation of the benzoxepane ring system enshrined in 1.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::338f22324cfd015c1ad25f898df44bcd https://doi.org/10.1016/j.tetlet.2006.04.011 Zobrazit plný text záznamu Full Text from ScienceDirect