Electrochemical and optical study of rhenium layers formed on gold electrodes
Autor: | J.O. Zerbino, María Elisa Martins, Carlos F. Zinola, A.M. Castro Luna, Eduardo Méndez |
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Rok vydání: | 2002 |
Předmět: | |
Zdroj: | Journal of Electroanalytical Chemistry. 521:168-174 |
ISSN: | 1572-6657 |
DOI: | 10.1016/s0022-0728(02)00690-3 |
Popis: | Films obtained after cathodic polarization at Ec, −0.2 V≤Ec≤0.1 V (vs. RHE), in aqueous acid perrhenate have been investigated using cyclic voltammetry and ellipsometry. The thickness and optical indices corresponding to the electrodeposited rhenium layer were calculated. The results indicate the formation of a composite layer, with a volumetric fraction of about 30% of metallic rhenium and hydrogen occlusion. |
Databáze: | OpenAIRE |
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