Electronic transport in σ- and π- conjugated polymers: Common features

Autor: Milan Stolka, Martin A. Abkowitz
Rok vydání: 1991
Předmět:
Zdroj: Synthetic Metals. 43:3385-3388
ISSN: 0379-6779
DOI: 10.1016/0379-6779(91)91309-x
Popis: Recent Time-Of-Flight studies of hole transport in θ-conjugated polymers , a methoxyphenyl-substituted poly(p-phenylene vinylene) (PPV) [1,2] and poly(p-phenylene sulfide) (PPS) [3,4] revealed that the features of transport are similar to those observed in σ-conjugated polymers such as polysilylenes. The close resemblance of transport behavior of both groups of polymers to molecularly doped polymers and poly(N-vinyl-carbazole) suggests that intersite hopping is the predominant mechanism of hole transport even in π-conjugated polymers.
Databáze: OpenAIRE