Kuroshines A and B, new alkaloids from Zoanthus kuroshio
Autor: | Wan Chun Lai, Yuan-Bin Cheng, Fang Rong Chang, Yu Chi Tsai, Chih Chin Lan, Wei Chun Liu, Yang Chang Wu, Michael Y. Chiang |
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Rok vydání: | 2014 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 55:5369-5372 |
ISSN: | 0040-4039 |
DOI: | 10.1016/j.tetlet.2014.07.101 |
Popis: | A chemical investigation of Zoanthus kuroshio has yielded two new alkaloids, kuroshines A (1) and B (2). The compounds possess a densely functionalized ring system on the basis of the zoanthamine frames. The structures of 1 and 2 were elucidated through interpretation of spectroscopic methods, especially 2D NMR techniques (COSY, HMQC, HMBC, and ROESY). The absolute stereochemistry of 1 was further confirmed by an X-ray single crystallographic analysis using a mirror Cu-Kα radiation. |
Databáze: | OpenAIRE |
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