Preparation of dinuclear iron carbonyl compounds containing a three-electron CH2-S bridging fragment

Autor:	Lorna Linford, Anthonie Lombard, Helgard G. Raubenheimer
Rok vydání:	1989
Předmět:	Inorganic Chemistry Stereochemistry Chemistry Organic Chemistry X-ray crystallography Molecule Crystal structure Electron Physical and Theoretical Chemistry Iron Carbonyl Compounds Ultraviolet radiation Medicinal chemistry Bond cleavage
Zdroj:	Organometallics. 8:2062-2063
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om00110a038
Popis:	Dithioacetals, CH 2 (SR 1 )(SR 2 ), reacted with Fe(CO) 5 under UV irradiation to give, after scission of an S-C bond, the butterfly complexes [Fe 2 (CO) 6 (μ-SR 1 )(μ-CH 2 SR 2 )-C,S[ [R 1 R 2 =CH 2 SCH 2 or (CH 2 ) 3 and R 1 =R 2 =Me]. A crystal structure determination and NMR study confirmed the similar structures and novel CH 2 -S bridging units in all these complexes
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::335c64057b5704bf61151e7b30cd7d5a https://doi.org/10.1021/om00110a038 Zobrazit plný text záznamu