Luminescence of XeCl* and XeBr* exciplex molecules initiated by a longitudinal pulsed discharge in a three-component mixture of Xe with CsCl and CsBr vapors

Autor:	Yu. V. Zhmenyak, V. A. Kel’man, M. S. Klenovskii, Yu. O. Shpenik
Rok vydání:	2013
Předmět:	Materials science Analytical chemistry chemistry.chemical_element Excimer Alkali metal Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Xenon chemistry Yield (chemistry) Inert gas Luminescence Excitation Power density
Zdroj:	Optics and Spectroscopy. 114:197-204
ISSN:	1562-6911 0030-400X
DOI:	10.1134/s0030400x13010141
Popis:	The excitation of simultaneous luminescence of XeCl* and XeBr* exciplex molecules in a longitudinal pulsed-periodic discharge has been studied. To generate exciplex molecules, a three-component mixture of xenon with cesium bromide and chloride vapors was used. Spectral, energetic, and pulse-temporal characteristics of the discharge have been investigated, and the dependences of the UV luminescence yield on the composition and excitation conditions of the mixture have been studied. The average specific power of the discharge UV radiation in the Xe-CsBr-CsCl mixture has been determined to be 0.25 W/cm3, which corresponds to the total efficiency value ∼0.7%. Also, mechanisms by which exciplex molecules are formed in a low-pressure vapor-gas mixture of the inert gas with halogenides of alkali metals have been considered.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3340908c3f418ea51e271ec5e9aaadcd https://doi.org/10.1134/s0030400x13010141 Zobrazit plný text záznamu Plný text ve formátu PDF