Influence of Cu content on the mechanical properties and corrosion resistance of Mg-Zn-Ca bulk metallic glasses

Autor: Chang Li, Song Jingguo, Zhu Jian, Xidong Hui, Xiaohua Chen, Zhao Yanfeng
Rok vydání: 2014
Předmět:
Zdroj: International Journal of Minerals, Metallurgy, and Materials. 21:487-493
ISSN: 1869-103X
1674-4799
Popis: Mg66.2Zn28.8Ca5)100−xCux (at%, x = 0, 1, 3, and 5) bulk metallic glasses (BMGs) of 2 mm in diameter were prepared by the con- ventional copper mold injection casting method. Besides, the influence of Cu content on the microstructure, thermal stability, mechanical properties, and corrosion behavior of Mg−Zn−Ca BMGs was investigated. It is found that the addition of Cu decreases the glass-forming ability of Mg−Zn−Ca BMGs. Crystalline phases are precipitated at a higher Cu content, larger than 3at%. The compressive fracture strength of Mg−Zn−Ca BMGs is enhanced by the addition of Cu. With the formation of in-situ composites, the compressive strength of the Mg−Zn−Ca alloy with 3at% Cu reaches 979 MPa, which is the highest strength among the Mg−Zn−Ca alloys. Furthermore, the addition of Cu also results in the increase of corrosion potential and the decrease of corrosion current density in Mg−Zn−Ca BMGs, thereby delaying their biodegradability.
Databáze: OpenAIRE