Heterogeneous Cyanation Reaction of Aryl Halides Catalyzed by a Reusable Palladium Schiff Base Complex in Water

Autor: Huiliang Jiang, Huixian Wei, Jianzhong Jiang, Chun Cai
Rok vydání: 2013
Předmět:
Zdroj: Catalysis Letters. 143:1195-1199
ISSN: 1572-879X
1011-372X
DOI: 10.1007/s10562-013-1057-8
Popis: Heterogeneous cyanation reaction of aryl halides with K4[Fe(CN)6] was studied over a polymer supported macrocyclic palladium complex. The reaction proceeded smoothly by adding TX100 (2 wt%) in water without organic solvents. The catalyst exhibited effective catalytic activities to afford the corresponding products in good to excellent yields. Furthermore, the catalyst could be easily recovered and reused for several times without a significant loss of its activity. Heterogeneous cyanation reaction of aryl halides with K4[Fe(CN)6] was studied over a polymer supported macrocyclic palladium complex. The reaction proceeded smoothly by adding TX100 (2 wt%) in water without organic solvents.
Databáze: OpenAIRE