Microwave-assisted graft polymerization of ε-caprolactone onto magnetite
| Autor: | Holger Scharf, Izabell Craciunescu, Jürgen Liebscher, Alexandrina Nan, Rodica Turcu, Ovidiu Pana |
|---|---|
| Rok vydání: | 2009 |
| Předmět: |
Materials science
Polymers and Plastics Organic Chemistry chemistry.chemical_element Ring-opening polymerization chemistry.chemical_compound X-ray photoelectron spectroscopy chemistry Polymerization Chemical engineering Polymer chemistry Materials Chemistry Magnetic nanoparticles Fourier transform infrared spectroscopy Tin Caprolactone Magnetite |
| Zdroj: | Journal of Polymer Science Part A: Polymer Chemistry. 47:5397-5404 |
| ISSN: | 1099-0518 0887-624X |
| DOI: | 10.1002/pola.23589 |
| Popis: | The graft polymerization of e-caprolactone (e-CL) onto magnetite was carried out under microwave irradiation in the presence of tin(II) 2-ethylhexanoate. The molar ratio of e-CL to tin(II) 2-ethylhexanoate was 300, whereas the molar ratio of e-CL to magnetite was 5. The chemical structures of the obtained poly(e-caprolactone) coated magnetic nanoparticles were characterized by FTIR and XPS spectroscopy. These magnetic-polymer hybrid nanostructures were further investigated by X-ray diffraction and magnetization measurements. The morphology of the magnetic core-shell nanostructures were determined by TEM. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5397–5404, 2009 |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text