Synthesis and Metal Ion Recognition Properties of a Novel Chiral Calix[4](azoxa)crown-7

Autor:	Shahabuddin Memon, Mustafa Yilmaz, Erdal Kocabas, Aysegul Karakucuk, Abdulkadir Sirit
Rok vydání:	2005
Předmět:	Chemistry Inorganic chemistry General Chemistry Carbon-13 NMR Alkali metal Ion Metal chemistry.chemical_compound Transition metal visual_art Polymer chemistry visual_art.visual_art_medium Selectivity Chirality (chemistry) Derivative (chemistry)
Zdroj:	Supramolecular Chemistry. 17:251-256
ISSN:	1029-0478 1061-0278
DOI:	10.1080/10610270412331337321
Popis:	A novel chiral calix[4](azoxa)crown-7 (9) has been synthesized and its metal ion recognition properties investigated. The starting reagents, chiral diamine 5 and calix[4]arene diacid chloride derivative 8, were prepared according to literature methods. 1H and 13C NMR data show that 9 exists in a cone conformation. In liquid–liquid extraction experiments, 9 exhibits selectivity for Li+ among the other alkali metals and a good extraction ability for transition metal cations, suggesting its potential use in different fields, such as a sensor for ions as well as for chiral molecules.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::32deafeabe0fb22f13cbc716d2ed0425 https://doi.org/10.1080/10610270412331337321 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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