A facile synthesis of the sex pheromone of Grapholitha molesta

Autor:	Feng-lan Huang, Jian-ping Yong, Shu-zhen Bai, Jiu-ming Li
Rok vydání:	2012
Předmět:	1 8-Octanediol Plant Science General Chemistry Medicinal chemistry General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound chemistry Nitric acid Yield (chemistry) Sex pheromone Wittig reaction Proton NMR Sodium nitrite Spectral data
Zdroj:	Chemistry of Natural Compounds. 48:103-105
ISSN:	1573-8388 0009-3130
DOI:	10.1007/s10600-012-0168-6
Popis:	The sex pheromone of Grapholitha molesta, (Z/E)-8-dodecylen-1-ol acetate, was easily synthesized in an overall yield of 41.5% with 1,8-octanediol as starting material via mono-esterification, PCC oxidation, and Witting reactions. The Z/E ratio is 83:17. Configuration transformation of Z/E 83:17 compound with sodium nitrite and nitric acid resulted in the production of a compound with Z/E 24:76. The products were confirmed by IR, 1H NMR, and MS spectral data.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::32db19b3c43b1f06b1a2e9fdfc203a83 https://doi.org/10.1007/s10600-012-0168-6 Zobrazit plný text záznamu Plný text ve formátu PDF