A sensitive and rapid UV–vis spectrophotometry for organophosphorus pesticides detection based on Ytterbium (Yb3+) functionalized gold nanoparticle
| Autor: | Yuan Li, Rong Hu, Qing-Jiao Luo, Zongbao Chen, Ping Qiu |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Detection limit
Maximum Residue Limit medicine.diagnostic_test Chemistry 010401 analytical chemistry Nanoparticle 02 engineering and technology General Chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Thiophosphate Absorbance chemistry.chemical_compound Ultraviolet visible spectroscopy Spectrophotometry medicine media_common.cataloged_instance European union 0210 nano-technology media_common Nuclear chemistry |
| Zdroj: | Chinese Chemical Letters. 29:1845-1848 |
| ISSN: | 1001-8417 |
| DOI: | 10.1016/j.cclet.2018.11.016 |
| Popis: | A kind of sensitive, rapid, and simple spectrophotometry based on a Ytterbium (Yb3+) functionalized gold nanoparticle (Au NPs-Yb) was developed for detection of organophosphorus pesticides (OPs). Prepared AuNPs possess oxygen-containing functional groups and strong complexation reaction with Yb3+. While oxygen-containing thiophosphate in the OPs molecule can combine with Yb3+ as a cross-linking molecule to produce insoluble yetterbium phosphate, resulting in the aggregation of AuNPs and great decrease in ultraviolet absorbance strength at 520 nm by ultraviolet visible (UV–vis) spectrophotometer. Under the optimized conditions, a linear relationship between the absorbance of AuNPs and OPs concentration ranged from 0.05 μg/L to 6.0 μg/L with limit of detection for 0.03 μg/L (S/N = 3), which is far lower than the maximum residue limit (0.01 ppm) in the European Union pesticides database. Therefore, this assay has potential application in the determination of OPs in the field of environmental and food monitoring. |
| Databáze: | OpenAIRE |
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