Synthesis of telechelic polyacrylates with unsaturated end-groups

Autor:	Robert H. Grubbs, Christopher W. Bielawski, Jagdish M. Jethmalani
Rok vydání:	2003
Předmět:	chemistry.chemical_classification Polymers and Plastics Atom-transfer radical-polymerization Butyl acrylate Organic Chemistry Radical polymerization Polymer Macromonomer chemistry.chemical_compound Photopolymer chemistry Polymerization Polymer chemistry Materials Chemistry Prepolymer
Zdroj:	Polymer. 44:3721-3726
ISSN:	0032-3861
DOI:	10.1016/s0032-3861(03)00178-2
Popis:	A convenient, one-pot synthesis of telechelic and semi-telechelic polyacrylates with unsaturated end-groups has been developed. Atom transfer radical polymerization of methyl or n -butyl acrylate was initiated with either ethyl α-bromomethylacrylate or methyl dichloroacetate, as a monofunctional or difunctional initiator, respectively, and mediated with various Cu/amine complexes. Addition of excess ethyl 2-bromomethylacrylate was found to not only immediately quench the polymerization but also installed 2-carbethoxyallyl moieties on the ends of the polymer chains. The telechelic polymers were found to undergo thermally or photochemically induced crosslinking reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::329a26d9059a7111b0a683ad3b9cda53 https://doi.org/10.1016/s0032-3861(03)00178-2 Zobrazit plný text záznamu Full Text from ScienceDirect