Illuminating the nature and behavior of the active center: the key for photocatalytic H2production in Co@NH2-MIL-125(Ti)

Autor:	Dmitrii Osadchii, Manuel Monte, Matvey V. Fedin, Sonia Castellanos, Alma I. Olivos Suarez, Giovanni Agostini, Jara G. Santaclara, Jorge Gascon, Sergey L. Veber, Maxim A. Nasalevich, Ana Iglesias-Juez
Rok vydání:	2018
Předmět:	X-ray absorption spectroscopy Materials science Absorption spectroscopy Renewable Energy Sustainability and the Environment 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences 0104 chemical sciences law.invention Characterization (materials science) Active center Characterization methods law Photocatalysis General Materials Science 0210 nano-technology Electron paramagnetic resonance
Zdroj:	Journal of Materials Chemistry A. 6:17318-17322
ISSN:	2050-7496 2050-7488
Popis:	Advanced atomically resolved characterization methods unveil the mechanism of a promising photocatalytic Co@MOF(Ti) system for H2 production. The combination of X-ray absorption spectroscopy (XAS) and electron paramagnetic resonance (EPR) experiments allows for the characterization of atomic and electronic rearrangements in the photoinduced species. This information provides the basis for the optimization of photocatalyst design.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3297f1b25395711195ae458d51e2f985 https://doi.org/10.1039/c8ta05735d Zobrazit plný text záznamu