Autor: G. P. Dukhanin, V. I. Glazov, V. A. Losev
Rok vydání: 2002
Předmět:
Zdroj: Russian Journal of Applied Chemistry. 75:891-893
ISSN: 1070-4272
DOI: 10.1023/a:1020364008208
Popis: The partial pressure of sodium nitrite in the system NaNO2-KNO3 was measured at 798, 823, and 848 K. The dependence of the logarithm of the NaNO2 pressure on inverse temperature is presented. Coefficients A and B of the Clausius-Clapeyron equation and the partial molar heats of vaporization are calculated. The activity and activity coefficient of sodium nitrite are determined. The dependences of ac- tivity and activity coefficient of sodium nitrite and potassium nitrate are presented as functions of composition of the NaNO2-KNO3 system. The consistency of the activity coefficients is verified using the Redlich-Kister integral.
Databáze: OpenAIRE