Versatile coordination behaviour of Ph2AsCH2AsPh2 with Ru(II)

Autor:	Simon J. Higgins, Jamie F. Bickley, Edmund Leary, Victoria Barton, Fouzi Mouffouk, Joanne Ledger, Louise A. Cain
Rok vydání:	2004
Předmět:	Inorganic Chemistry Crystallography Mole ratio biology Chemistry Materials Chemistry biology.protein Crystal structure Physical and Theoretical Chemistry Electrochemistry Medicinal chemistry Isomerization ASPH
Zdroj:	Inorganica Chimica Acta. 357:4488-4495
ISSN:	0020-1693
DOI:	10.1016/j.ica.2004.07.002
Popis:	Treatment of ‘RuCl 3 · 3H 2 O’ with Ph 2 AsCH 2 AsPh 2 (dpam) in hot EtOH gives either trans -[RuCl 2 (dpam-As,As′)(dpam-As) 2 ] ( 1 ), or cis -[RuCl 2 (dpam-As,As′) 2 ] ( 2 ), depending on the mole ratio. On exposure to light, solutions of 2 isomerise to trans -[RuCl 2 (dpam-As,As′) 2 ] ( 3 ). Treatment of [RuCl 2 (PPh 3 ) 3 ] with two equivalents of dpam in CH 2 Cl 2 gave a mixture of two products, from which trans -[RuCl 2 (PPh 3 ) (dpam-As,As′)(dpam-As)] ( 4 ) was isolated by recrystallisation. The crystal structures of 1–4 are reported. Complexes 1 – 3 in CH 2 Cl 2 undergo electrochemical oxidation to Ru(III), and the Ru(III) form of 2 undergoes isomerisation on the voltammetric timescale to the Ru(III) form of 3 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::326ffa11e78d6372ce25a981568d3665 https://doi.org/10.1016/j.ica.2004.07.002 Zobrazit plný text záznamu Full Text from ScienceDirect