α,ω-Alkanedithiol cross-linking of high vinyl 3,4-polyisoprene

Autor:	Shanganyane P. Hlangothi, C. D. Woolard, Buyiswa G. Hlangothi
Rok vydání:	2014
Předmět:	Addition reaction Materials science Polymers and Plastics Natural rubber General Chemical Engineering visual_art Polymer chemistry Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Vinyl polymer
Zdroj:	Plastics, Rubber and Composites. 43:217-224
ISSN:	1743-2898 1465-8011
Popis:	This paper evaluates the ability of α,ω-alkanedithiols to cross-link high vinyl 3,4-polyisoprene rubber (represented by Isogrip) through the thiol-ene addition reaction and provides microstructural insights into where cross-linking takes place. The thiol-ene reactions are the hydrothiolation of a C = C bond, which can be initiated in a number of ways. It has been postulated that organic peroxides are very effective in initiating such cross-links and that α,ω-alkanedithiol-ene cross-linking of high vinyl 3,4-polyisoprene primarily takes place on the α-carbon of the unsaturated sites of the rubber chains.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::325cab9cffbaa638ad34031a7fe9d470 https://doi.org/10.1179/1743289814y.0000000092 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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