Non-adiabatic transitions from the I2(E) induced by the transition dipole moment of I2(E–D) and the electric dipole moment of collision partners

Autor:	M.E. Akopyan, S.S. Lukashov, Yu.D. Maslennikova, A.S. Torgashkova, S.A. Poretsky, Anatoly Pravilov
Rok vydání:	2008
Předmět:	Bond dipole moment Dipole Electric dipole moment Chemistry Transition dipole moment General Physics and Astronomy Overtone band Physical and Theoretical Chemistry Atomic physics Electric dipole transition Magnetic dipole Electron magnetic dipole moment
Zdroj:	Chemical Physics Letters. 458:29-34
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2008.04.062
Popis:	Optical–optical double resonance spectroscopy is used to obtain total rate constants, electronic branching ratios, and vibrational product state distributions for non-adiabatic transitions among the first-tier ion-pair states of the I 2 molecule excited to the E 0 g + , v E = 8 , 13 , 19 ; J E ≈ 55 rovibronic levels in collisions with M = CD 3 I and CH 3 COCH 3 . It is shown that I 2 ( E → M D ) near-resonant transitions are caused by the interaction between the transition dipole moment of I 2 (E–D) and the permanent electric dipole moment of M . The I 2 (D) state vibrational levels populated due to polarization interaction accompanied by quasi-resonance excitation of the collision partner are also observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::325c73679fccdd8b89ec13cbd22c8449 https://doi.org/10.1016/j.cplett.2008.04.062 Zobrazit plný text záznamu Full Text from ScienceDirect