Carbonyl ruthenium(III) complexes with 1,10-phenanthroline and 2,2′-bipyridine
| Autor: | Florian P. Pruchnik, Ewa Gałdecka, Zdzisław Gałdecki, Andrzej Kowalski |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
Formic acid
Phenanthroline chemistry.chemical_element Crystal structure Photochemistry Medicinal chemistry 2 2'-Bipyridine law.invention Ruthenium Inorganic Chemistry chemistry.chemical_compound chemistry Octahedron law Materials Chemistry Physical and Theoretical Chemistry Electron paramagnetic resonance Hyperfine structure |
| Zdroj: | Polyhedron. 18:2091-2097 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/s0277-5387(99)00079-0 |
| Popis: | The reaction of ruthenium trichloride with 1,10-phenanthroline or 2,2′-bipyridine in formic acid leads to the formation of ruthenium(III) carbonyl complexes: [RuCl3(CO)(phen)], 1, and [RuCl3(CO)(bpy)], 2. The crystal structures of the complexes have been determined by single-crystal X-ray analysis. Both complexes have distorted octahedral structures with CO ligands in the trans coordination site relative to the nitrogen atom. The EPR spectra of complexes 1 and 2 dissolved in DMF have been investigated. For both compounds a hyperfine structure has been observed for g3 in the spectra. |
| Databáze: | OpenAIRE |
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