Ru(II)-Catalyzed C–H Activation and Alkyne Annulation Reaction of Phenyl Indandiones: Synthesis of Spirobi[indene]diones

Autor: Sanjib Gogoi, Bidisha R. Bora, Sabera Sultana, Bipul Sarma
Rok vydání: 2022
Předmět:
Zdroj: Synthesis. 54:2907-2915
ISSN: 1437-210X
0039-7881
Popis: A Ru(II)-catalyzed synthesis of spirobi[indene]dione from phenyl indandione and alkyne is reported. This metal-catalyzed cyclization reaction proceeds through hydroxy group directed C(sp2)–H bond activation, keto–enol tautomerization and alkyne annulation pathways.
Databáze: OpenAIRE