Encapsulation of metallo-porphyrins into water-soluble amphipatic dendrigrafts
| Autor: | Michel Schappacher, Alain Deffieux |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Hydrodynamic radius Materials science Polymers and Plastics Organic Chemistry Dispersity Nanocontainer macromolecular substances Polymer chemistry.chemical_compound chemistry Polymer chemistry polycyclic compounds Materials Chemistry Copolymer Polystyrene Macromolecule |
| Zdroj: | Polymer. 45:4633-4639 |
| ISSN: | 0032-3861 |
| DOI: | 10.1016/j.polymer.2004.05.022 |
| Popis: | Newly prepared water-soluble amphipatic hyperbranched organic polymers are used as nanocontainer and as carriers for large metal-organic molecules such as metallo-porphyrins. The hydrosoluble dendrigrafts are constituted by a polystyrene hydrophobic core surrounded by a polyvinyl ether hydrophilic shell. These nanometer-sized amphipatic macromolecules with an average diameter of about 100 nm and narrow polydispersity are fully soluble in aqueous media. Their capacity to encapsulate and transport metallo-porphyrins in aqueous media is investigated. Complexation studies show that up to several thousands of guest molecules can be embedded into each amphipatic dendrigraft macromolecule. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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