Selective Oxidation ofn-Butane and Isobutane Catalyzed by Boron Nitride

Autor:	Juan M. Venegas, Carlos A. Carrero, Joseph T. Grant, William P. McDermott, Ive Hermans, Samuel P. Burt, Jack Micka
Rok vydání:	2017
Předmět:	Chemistry Organic Chemistry Kinetics Inorganic chemistry Hexagonal boron nitride Butane 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Catalysis 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Adsorption Boron nitride Isobutane Dehydrogenation Physical and Theoretical Chemistry 0210 nano-technology
Zdroj:	ChemCatChem. 9:2118-2127
ISSN:	1867-3880
Popis:	Hexagonal boron nitride (hBN) is presented as an outstanding catalyst for the selective production of C4 olefins by the oxidative dehydrogenation of n-butane and isobutane. Unlike catalysts reported previously, hBN limits the amount of undesired COx and instead forms C2 and C3 olefins as the main side products. Kinetic experiments suggest a mechanism in which the rates of n-butane and isobutane consumption are dependent on O2 adsorption. Kinetic and spectroscopic insights are used to formulate mechanistic hypotheses for the formation mechanisms of C2–C4 olefins.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::31e52bf0d216080ead33656bdbb0cc43 https://doi.org/10.1002/cctc.201601686 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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