Design of coherent anode materials with 0D Ni3S2nanoparticles self-assembled on 3D interconnected carbon networks for fast and reversible sodium storage
| Autor: | Xu Zhao, Wei Cai, Jian Cao, Jiangyu Li, Robert C. Massé, Hong-En Wang, Jiehe Sui, Guozhong Cao |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Nanocomposite Renewable Energy Sustainability and the Environment Diffusion Nanoparticle chemistry.chemical_element Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Redox 0104 chemical sciences Anode Nanomaterials chemistry General Materials Science 0210 nano-technology Carbon |
| Zdroj: | Journal of Materials Chemistry A. 5:7394-7402 |
| ISSN: | 2050-7496 2050-7488 |
| DOI: | 10.1039/c7ta01056g |
| Popis: | There has been tremendous progress in development of nanomaterials for energy conversion and storage, with sodium-ion batteries (SIBs) attracting attention because of the high abundance of raw materials and low cost. However, inferior cycling stability, sluggish reaction kinetics, and poor reversibility hinder their practical applications. In the present study, Ni3S2/carbon nanocomposites with coherent nanostructures were successfully used as anodes in half- and full-cells. Outstanding cycling and rate performances are attributed to a synergistic effect between the Ni3S2 nanoparticles and interconnected carbon networks. The coherent porous framework effectively alleviated volume changes of Ni3S2, shortened the Na+ diffusion path, and accelerated electron transport and ionic diffusion during the electrochemical reaction. More importantly, conversion reaction products can be confined by the entangled carbon networks, leading to reversible redox reactions as demonstrated in ex situ XRD studies. The coherent Ni3S2/C nanocomposites demonstrated a highly reversible charge capacity of 453 and 430 mA h g−1 at a current density of 0.1 and 0.4 A g−1 over 100 cycles, respectively. At a current density of 2.0 A g−1, high rate capacities of 408 mA h g−1 can be attained over 200 cycles. The high performance of Na3V2(PO4)3/Ni3S2 full-cells enrich prospects for future practical applications. |
| Databáze: | OpenAIRE |
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