Synthesis and Structures of All Possible Cr(CO)3 Complexes of Triptycene

Autor: Michinori Ōki, and Hironobu Okuhara, Shinji Toyota
Rok vydání: 1997
Předmět:
Zdroj: Organometallics. 16:4012-4015
ISSN: 1520-6041
0276-7333
DOI: 10.1021/om9703705
Popis: Mono-, bis-, and tris(tricarbonylchromium) complexes of triptycene were synthesized by the reaction of triptycene with Cr(CO)6. The stereochemistry of the two isomeric bimetallic complexes of Cs and C2v symmetries was determined from the NMR spectra. X-ray structures of the bimetallic (Cs) and trimetallic complexes are presented.
Databáze: OpenAIRE