Synthesis of homochiral cyclopentane derivatives by Beckmann fragmentation of 1-substituted 2-norbornanones

Autor:	E. Teso Vilar, C. Maichle, L. R. Subramanian, S. De La Moya Cerero, A. Garcia Fraile, C. Diaz Oliva, A. Garcia Martinez
Rok vydání:	1994
Předmět:	Nitrile Bicyclic molecule Organic Chemistry Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Pyridine Beckmann rearrangement Lactam Organic chemistry Stereoselectivity Physical and Theoretical Chemistry Cyclopentane Bond cleavage
Zdroj:	Tetrahedron: Asymmetry. 5:949-954
ISSN:	0957-4166
Popis:	The fragmentation of 2-norbornanone oximes 2 was achieved by reaction with Tf2O/pyridine under mild reaction conditions, yielding homochiral (or racemic) cyclopentane derivativel.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::31643754b564efd43fc4a0a41420dec0 https://doi.org/10.1016/s0957-4166(00)86247-3 Zobrazit plný text záznamu