Synthesis and Crystal Structure of Cucurbit[6]uril Adduct of Hydrogen-bonded Cluster Complex [Mo3(μ3-Se)(μ2-O)3(H2O)6Cl3]+

Autor:	Alexander V. Virovets, Pavel A. Abramov, Maxim N. Sokolov, Eugenia V. Peresypkina, Vladimir P. Fedin
Rok vydání:	2007
Předmět:	Hydrogen Stereochemistry Supramolecular chemistry chemistry.chemical_element General Chemistry Crystal structure Condensed Matter Physics Biochemistry Adduct Catalysis Crystallography chemistry Molybdenum Cucurbituril Yield (chemistry) General Materials Science
Zdroj:	Journal of Cluster Science. 18:597-605
ISSN:	1572-8862 1040-7278
Popis:	Reaction of [MoOCl5]2− with in situ generated H2Se under hydrothermal conditions (4M HCl, 140 °C) leads to reduction of Mo(V) to Mo(IV) with the formation of a triangular cluster Mo3(μ3-Se)(μ-O) 3 4+ in high yield. It is present in HCl solutions as aqua chlorocomplex [Mo3(μ3-Se)(μ-O)3(H2O)6Cl3]+ which was isolated and structurally characterized as supramolecular adduct with cucurbit[6]uril (CB[6]), {[Mo3(μ3-Se)(μ-O)3(H2O)6Cl3]2CB[6]}Cl2·15H2O.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::315aaeb3fafeca3836aa1f11ca125516 https://doi.org/10.1007/s10876-007-0120-2 Zobrazit plný text záznamu Full text from SpringerLink