Efficient Preparation of 2,3-Disubstituted Cyclopropane-1-Carbonitriles via Selective Decarboxylation of 1-Cyanocyclopropane-1-Carboxylates

Autor:	Siran Qian, Weijian Ye, Lizhong Wang, Zhenjie Su, Cunde Wang
Rok vydání:	2017
Předmět:	chemistry.chemical_compound 010405 organic chemistry Chemistry Decarboxylation Yield (chemistry) Organic chemistry Stereoselectivity General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Cyclopropane
Zdroj:	Journal of Chemical Research. 41:636-640
ISSN:	2047-6507 1747-5198
DOI:	10.3184/174751917x15094552081161
Popis:	2,3-Disubstituted cyclopropane-1-carbonitriles were efficiently formed via a selective decarboxylation reaction of substituted 2-aroyl-3-aryl-1-cyano-cyclopropane-1-carboxylates in up to 92% yield. The structures of three typical compounds were confirmed by X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::31474caf874120345d5a44c23791c167 https://doi.org/10.3184/174751917x15094552081161 Zobrazit plný text záznamu Plný text ve formátu PDF