Effect of Molecular Orbital Distributions on Charge Transport Properties of Polymers Doped with Triphenylamine Derivatives
| Autor: | Sukekazu Aratani, Tsuneaki Kawanishi, Atsushi Kakuta |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
chemistry.chemical_classification
Tertiary amine Chemistry Stereochemistry Doping General Engineering General Physics and Astronomy Polymer Triphenylamine chemistry.chemical_compound Formalism (philosophy of mathematics) Chemical physics visual_art visual_art.visual_art_medium Molecular orbital Polycarbonate HOMO/LUMO |
| Zdroj: | Japanese Journal of Applied Physics. 35:2184 |
| ISSN: | 1347-4065 0021-4922 |
| DOI: | 10.1143/jjap.35.2184 |
| Popis: | The hole drift mobilities of polymers doped with triphenylamine derivatives including heterocyclic groups have been measured and the effect of molecular orbital distributions of triphenylamine derivatives on the charge transport properties has been studied. The temperature dependence of the mobilities of polymers doped with two kinds of triphenylamine derivatives has been analyzed using the disorder formalism presented by Bässler and co-workers[H. Bässler, Phys. Status Solidi B 175(1993) 15.] and it has been found that highest occupied molecular orbital (HOMO) distribution of the triphenylamine derivatives has little effect on the diagonal and off-diagonal disorder but has a large effect on the disorder-free mobility in this formalism. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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