Palladium-Catalyzed Carbonyl Allylation of Aldehydes by Allylic Cyclic Carbonates

Autor:	Chan Hee Park, S.‐B. Jang, Dong-Chul Park, Suk-Ku Kang
Rok vydání:	1995
Předmět:	inorganic chemicals Allylic rearrangement integumentary system organic chemicals Organic Chemistry food and beverages chemistry.chemical_element Catalysis chemistry.chemical_compound chemistry polycyclic compounds Organic chemistry Carbonate Palladium
Zdroj:	Synthetic Communications. 25:1359-1366
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397919508013837
Popis:	Palladium(O)-catalyzed allylation of aldehydes by allylic cyclic carbonates with SnCl2 proceeded smoothly to afford 1,3-diols with high diastereocontrol. For the exomethylene cyclic carbonate, allylation with aldehydes furnished 1,4-diols or 1,5-diols depending on amount of aldehydes.
Databáze:	OpenAIRE
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