The Effect of pH on Flame-Retardant Finishes for Cotton Prepared from THPC and Various Bases
| Autor: | George L. Drake, Arlen W. Frank |
|---|---|
| Rok vydání: | 1974 |
| Předmět: |
010302 applied physics
chemistry.chemical_classification Polymers and Plastics Base (chemistry) Trimethylamine 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences chemistry.chemical_compound Ammonia chemistry Sodium hydroxide Amide 0103 physical sciences Polymer chemistry Chemical Engineering (miscellaneous) Hydroxymethyl 0210 nano-technology Fire retardant Leveling effect |
| Zdroj: | Textile Research Journal. 44:292-298 |
| ISSN: | 1746-7748 0040-5175 |
| DOI: | 10.1177/004051757404400402 |
| Popis: | Various bases are compared for the neutralization of tetrakis(hydroxymethyl)phosphonium chloride (THPC) in flame-retardant finishes for cotton. In the THPC/amide process, the use of sodium hydroxide as the base results in a progressive decrease in add-on with increasing pH, whereas with trimethylamine and other strongly basic tertiary amines, the add-on is constant up to pH 10. Trimethylamine also has a leveling effect in the THPOH/ammonia process, where the difference is more subtle. The fabric properties of cotton printcloth, sateen, and flannelette finished with the THPC Me3N amide formulation are independent of pH in the 5.0-9.0 range. |
| Databáze: | OpenAIRE |
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