Demixing in the plasma created in capillary discharges with polymeric wall

Autor: A S Pashchina
Rok vydání: 2021
Předmět:
Zdroj: Journal of Physics: Conference Series. 2100:012002
ISSN: 1742-6596
1742-6588
DOI: 10.1088/1742-6596/2100/1/012002
Popis: The results of spectral diagnostics of erosion plasma obtained in a pulsed discharge in a capillary with an evaporating wall made of hydrogen-carbon and fluorine-carbon polymers - polymethylmethacrylate and polytetrafluoroethylene - are presented. It was found that in both cases the distribution of chemical elements along the discharge radius is highly inhomogeneous, and their concentration ratio differs significantly from that in the capillary wall. The mass of particles is a common sign characterizing the demixing degree of chemical elements and direction of diffusion flows in fluorine-carbon and hydrogen-carbon plasmas. In both cases, lightweight particles are concentrated in the central high-temperature region, while heavy ones run away onto the low-temperature peripheral region of the discharge. Estimates show that the thermal diffusion mechanism is quite capable for providing the observed demixing degree of chemical elements. Favorable conditions for thermal diffusion processes are formed in the layer adjacent to the capillary wall, where the intense dissociation of radicals occurs, and the temperature gradient reaches up to ΔT∼10 eV/mm.
Databáze: OpenAIRE