Mechanism of formation ofo-semiquinone metal complexes under mechanical pulse action on metal oxide-quinone-pyrocatechol systems

Autor: A. I. Aleksandrov, N. N. Bubnov, I. A. Aleksandrov, Ya. S. Lebedev, A. A. Dubinskii, R. R. Rakhimov, A. I. Prokof'ev
Rok vydání: 1999
Předmět:
Zdroj: Russian Chemical Bulletin. 48:323-329
ISSN: 1573-9171
1066-5285
DOI: 10.1007/bf02494557
Popis: The possibility of the mechanochemical synthesis of metal-containing mono-, bi-, and triradicals under mechanical pulse action on mixtures of metal oxides (CuO, ZnO, CdO, PbO, Al2O3, Ga2O3, Sb2O3, Bi2O3, Cr2O3, TiO2, GeO2, ZrO2, or SnO2) with quinone and pyrocatechol was examined. The reaction products are formed both on the surface of metal oxides and as individual solid phases. The mechanism of chemical processes that occur under the action of a single elastic wave pulse is proposed.
Databáze: OpenAIRE