Mechanism of formation ofo-semiquinone metal complexes under mechanical pulse action on metal oxide-quinone-pyrocatechol systems
Autor: | A. I. Aleksandrov, N. N. Bubnov, I. A. Aleksandrov, Ya. S. Lebedev, A. A. Dubinskii, R. R. Rakhimov, A. I. Prokof'ev |
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Rok vydání: | 1999 |
Předmět: | |
Zdroj: | Russian Chemical Bulletin. 48:323-329 |
ISSN: | 1573-9171 1066-5285 |
DOI: | 10.1007/bf02494557 |
Popis: | The possibility of the mechanochemical synthesis of metal-containing mono-, bi-, and triradicals under mechanical pulse action on mixtures of metal oxides (CuO, ZnO, CdO, PbO, Al2O3, Ga2O3, Sb2O3, Bi2O3, Cr2O3, TiO2, GeO2, ZrO2, or SnO2) with quinone and pyrocatechol was examined. The reaction products are formed both on the surface of metal oxides and as individual solid phases. The mechanism of chemical processes that occur under the action of a single elastic wave pulse is proposed. |
Databáze: | OpenAIRE |
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