Reactive polymers: design considerations, novel preparations and selected applications in organic chemistry

Autor:	G. D. Darling, W. A. Rolls, Jean M. J. Fréchet, Shinichi Itsuno, P.-Z. Lu, M. V. de Mefiahi
Rok vydání:	1988
Předmět:	chemistry.chemical_classification Reaction mechanism Chemistry General Chemical Engineering Catalyst support Enantioselective synthesis Chemical modification General Chemistry Polymer chemistry.chemical_compound Monomer Polymerization Surface modification Organic chemistry
Zdroj:	Pure and Applied Chemistry. 60:353-364
ISSN:	1365-3075 0033-4545
Popis:	Crosslinked reactive polymers with novel structures have been prepared from the corresponding monomers or by newly developed chemical modification reactions. These include the preparation of polymers with two or three carbon spacer groups between backbone and functionality, the first preparation of a Grignard reagent on an insoluble polymer, and some new copper m ediated c hemical modification reactions resulting in C-C bond formation. Novel applications of these polymers in asymmetric syntheses, regenerable polymeric protecting groups, supernucleophili c catalysts, polymeric separation media for HPLC, as well as aids in the determination of reaction mechanisms, have been investigated. Microenvironment effects within the polymer beads are shown to be important when considering the use of an insoluble reactive polymer
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::30e3ca063b58ec1a12a6405dfb65d1aa https://doi.org/10.1351/pac198860030353 Zobrazit plný text záznamu