Electrochemistry and Umpolung Reactions: New Tools for Solving Synthetic Challenges of Structure and Location

Autor:	Kevin D. Moeller, Feili Tang, Ceng Chen
Rok vydání:	2007
Předmět:	Electron transfer Polarity (physics) Chemistry Reagent Organic Chemistry Bond formation Photochemistry Electrochemistry Combinatorial chemistry Catalysis Umpolung
Zdroj:	Synthesis. 2007:3411-3420
ISSN:	1437-210X 0039-7881
Popis:	Electrochemistry is a powerful tool for initiating new umpolung reactions. In this paper, two examples are provided. One demonstrates the use of electrochemistry for reversing the polarity of known functional groups and triggering carbon-carbon bond formation. The second demonstrates the use of electrochemistry for reversing the polarity of a chemical reagent, a technique that allows for spatially locating synthetic transformations on addressable chips.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::30df9e530c24eda96b1a34bbdaad13d4 https://doi.org/10.1055/s-2007-990835 Zobrazit plný text záznamu