100% atom-economical and highly regio- and stereoselective iodosulfenylation of alkynes: a reagentless and sustainable approach to access (E)-β-iodoalkenyl sulfides and (Z)-tamoxifen

Autor: Appanapalli N. V. Satyanarayana, Nilanjana Mukherjee, Tanmay Chatterjee
Rok vydání: 2023
Předmět:
Zdroj: Green Chemistry. 25:779-788
ISSN: 1463-9270
1463-9262
DOI: 10.1039/d2gc04101d
Popis: A 100% atom-economical iodosulfenylation of alkynes is developed using only iodine and disulfides via the in situ formation of the corresponding sulfenyl iodide intermediates to access (E)-β-iodoalkenyl sulfides and (Z)-tamoxifen.
Databáze: OpenAIRE