CATALYTIC VAPOR PHASE HYDROFORELATION OF OLEFINS OVER POLYMER-IMMOBILIZED RHODIUM COMPLEXES

Autor:	Taiseki Kunugi, Hiromichi Arai, Takashi Kaneko
Rok vydání:	1975
Předmět:	chemistry.chemical_classification Silica gel Inorganic chemistry chemistry.chemical_element Propionaldehyde General Chemistry Polymer Rhodium Catalysis chemistry.chemical_compound chemistry Polymer chemistry Polystyrene Phosphine Hydroformylation
Zdroj:	Chemistry Letters. 4:265-268
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.1975.265
Popis:	The rhodium complex (–RhCl(CO)2) coordinatively bonded to the phosphine group on polystyrene coated over silica gel is an efficient catalyst for hydroformylation of olefins at 100°C at 1 atm in vapor phase. The rate expression of propionaldehyde formation was R = k[H2][C2H4][CO]−0.5.
Databáze:	OpenAIRE
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