Convenient Synthesis of 3-Cinnamoyl-2-styrylchromones: Reinvestigation of the Baker-Venkataraman Rearrangement

Autor: Gregor Schnakenburg, Olivia Neumann, Olga N. Kataeva, Pia Königs, Siegfried R. Waldvogel
Rok vydání: 2010
Předmět:
Zdroj: European Journal of Organic Chemistry. 2010:6417-6422
ISSN: 1434-193X
DOI: 10.1002/ejoc.201000957
Popis: An efficient and straightforward, one-pot sequence gives access to highly functionalized 3-cinnamoyl-2-styrylchromones in excellent yields. The low solubility of the target molecules allows convenient isolation. The formation of an α,α-dicinnamoylated acetophenone, as a consequence of a two-fold Baker-Venkataraman sequence, has to be anticipated.
Databáze: OpenAIRE