Regio- and diastereo-chemically controlled photocycloaddition of an arene and an alkene linked by a chiral auxiliary

Autor:	Akira Tai, Tadao Hakushi, Norio Nishiyama, Takashi Sugimura
Rok vydání:	1994
Předmět:	chemistry.chemical_classification Chiral auxiliary Intramolecular reaction Alkene Stereochemistry Organic Chemistry Diastereomer Ring (chemistry) Catalysis Cycloaddition Inorganic Chemistry chemistry.chemical_compound chemistry Intramolecular force Physical and Theoretical Chemistry
Zdroj:	Tetrahedron: Asymmetry. 5:1163-1166
ISSN:	0957-4166
Popis:	Intramolecular meta -arene-alkene photocycloaddition of 1b , the substrate having a chiral auxiliary as a linking bridge between the arene and the alkene, resulted in high diastereofacial differentiation of the alkene at the addition step and sufficient regiocontrol of the subsequent ring closure step to give a single diastereomer 4 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::305c0316d15bd059fa3417b958f83df9 https://doi.org/10.1016/0957-4166(94)80147-9 Zobrazit plný text záznamu