Über metallalkyl- und arylverbindungen LV. Cyclopentadienyl- und indenyl-verbindungen des kaliums und natriums
| Autor: | Falk Olbrich, Volker Jordan, Erwin Weiss, Ulrich Behrens |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
Steric effects
PMDTA Sodium Potassium Organic Chemistry Inorganic chemistry chemistry.chemical_element Crystal structure Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Cyclopentadienyl complex Materials Chemistry Combined result Physical and Theoretical Chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 517:81-88 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(95)05988-2 |
| Popis: | The syntheses and crystal structures of the following solvated compounds are described: [cyclopentadienyl potassium(Et 2 O)] n ( 1 ) (multidecker structure), [indenyl sodium(PMDTA)] ( 2 ) (PMDTA = N,N,N′,N″N″-pentamethyldiethylenetriamine) (monomeric), [indenyl potassium(TMEDA)] n ( 3 ) (TMEDA = N,N,N′,N′-tetramethylenediamine) (monomeric), [indenyl potassium(PMDTA)] n ( 4 ) (polymeric, zig-zag chain). The different coordination modes are the combined result of electrostatic and steric effects. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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