Applications of pore-expanded MCM-41 silica: 4. Synthesis of a highly active base catalyst

Autor:	Peter J. E. Harlick, Dharani D. Das, Abdelhamid Sayari
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Pore-expanded MCM-41 Materials science Base (chemistry) Process Chemistry and Technology Inorganic chemistry Hydrothermal treatment General Chemistry Catalysis chemistry Chemical engineering Amine gas treating Knoevenagel condensation
Zdroj:	Catalysis Communications. 8:829-833
ISSN:	1566-7367
Popis:	MCM-41 silica whose pores have been expanded by post-synthesis hydrothermal treatment in the presence of N,N-dimethyldecylamine exhibits a unique combination of large pores (up to 20 nm), pore volume (up to 3.5 cc/g) and surface area (>1000 m2/g). It was used to accommodate a large amount of amine groups (2.2 mmol/g); thus generating a highly active base catalyst for Knoevenagel condensation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::30406ed99da36c6c686dd84f65b34ed7 https://doi.org/10.1016/j.catcom.2006.09.012 Zobrazit plný text záznamu Full Text from ScienceDirect