Sulfonylmercuration of conjugated dienes. A facile route to allyl- and dienyl-sulfones

Autor:	Ove Andell, Jan-E. Bäckvall
Rok vydání:	1985
Předmět:	chemistry.chemical_compound Nucleophilic addition chemistry Organic Chemistry Drug Discovery Organic chemistry 1 3-Butadiene Regioselectivity Conjugated system Aliphatic compound Biochemistry Combinatorial chemistry Adduct
Zdroj:	Tetrahedron Letters. 26:4555-4558
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)88957-1
Popis:	Phenylsulfonylmercuration of 1,3-dienes gives mercury adducts, which on treatment with base afford phenylsulfonyldienes. In most cases there action proceeds regioselectively to give 2-(phenylsulfonyl)-1,3-dienes. These are useful synthetic intermediates and can be readily transformed to a variety of functionalized allylsulfones by Michael-type addition.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::302de89209573029e4d3ff7b210b96e1 https://doi.org/10.1016/s0040-4039(00)88957-1 Zobrazit plný text záznamu