THE REACTION OF METHYL RADICALS WITH METHYL ALCOHOL
Autor: | T. W. Shannon, A. G. Harrison |
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Rok vydání: | 1963 |
Předmět: | |
Zdroj: | Canadian Journal of Chemistry. 41:2455-2461 |
ISSN: | 1480-3291 0008-4042 |
DOI: | 10.1139/v63-361 |
Popis: | The photolysis of acetone in the presence of methyl alcohol and of methyl-d3 alcohol has been studied between 406 and 472° K. The rates and Arrhenius parameters for the following abstraction reactions have been determined:[Formula: see text] [Formula: see text] [Formula: see text]At 182 °C the rate of reaction [b] is found to be approximately four times greater than the rate of reaction [c]. |
Databáze: | OpenAIRE |
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