THE REACTION OF METHYL RADICALS WITH METHYL ALCOHOL

Autor: T. W. Shannon, A. G. Harrison
Rok vydání: 1963
Předmět:
Zdroj: Canadian Journal of Chemistry. 41:2455-2461
ISSN: 1480-3291
0008-4042
DOI: 10.1139/v63-361
Popis: The photolysis of acetone in the presence of methyl alcohol and of methyl-d3 alcohol has been studied between 406 and 472° K. The rates and Arrhenius parameters for the following abstraction reactions have been determined:[Formula: see text] [Formula: see text] [Formula: see text]At 182 °C the rate of reaction [b] is found to be approximately four times greater than the rate of reaction [c].
Databáze: OpenAIRE