Association of chitosan in the presence of an anionic surfactant in aqueous-glycerol solutions
Autor: | S. V. Shilova, A. Ya. Tret’yakova, V. P. Barabanov |
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Rok vydání: | 2017 |
Předmět: |
Aqueous solution
General Chemical Engineering technology industry and agriculture macromolecular substances 02 engineering and technology General Chemistry equipment and supplies 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Fluorescence Sodium tetradecyl sulfate 0104 chemical sciences carbohydrates (lipids) Chitosan chemistry.chemical_compound chemistry Dynamic light scattering Pulmonary surfactant Glycerol medicine 0210 nano-technology Macromolecule medicine.drug Nuclear chemistry |
Zdroj: | Russian Journal of Applied Chemistry. 90:1372-1378 |
ISSN: | 1608-3296 1070-4272 |
DOI: | 10.1134/s1070427217080298 |
Popis: | The effect of additions of sodium tetradecyl sulfate as an anionic surfactant on the association of chitosan macromolecules in aqueous-glycerol solutions was studied by fluorescence probe spectroscopy and dynamic light scattering. Associates of 40–170 nm size are formed on reaching a certain critical concentration of chitosan in solutions. The critical association concentration of chitosan in solutions containing 10–30 vol % glycerol is higher than in aqueous solutions. Formation of chitosan–surfactant complexes enhances the tendency of chitosan macromolecules to association in water–glycerol mixed solvents. |
Databáze: | OpenAIRE |
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